InotungamirwaSecondary dzidzo uye zvikoro

Halogens: mumuviri ehupfumi, makemikari ehupfumi. The Kushandiswa yeimwe pakati halogens vavo

The halogens mu periodic table kuruboshwe yomuchinda magasi. Izvi hunokachidza esimbi zvinhu shanu muboka 7 Periodic Table. Izvi zvinosanganisira fluorine, kuiisa chlorine, bromine, ayodhini uye astatine. Kunyange astatine radioactive uye ane chete kwenguva pfupi isotopes, izvozvo haazvibati sezvo ayodhini uye inowanzonzi seva halogens. Sezvo halogen zvinhu zviri Valence maerekitironi nomwe, inoda chimwe chete mamwe Erekitironi kuti vaumbe octet wakakwana. mamirire Izvi zvinoita kuti uwane basa pane mamwe mapoka vasiri simbi.

General unhu

Halogens vanoumba diatomic Morekuru (X 2 mhando apo X iri halogen) - fomu-akatsiga kuvapo halogens sezvo vakasununguka masero. Contact pamusoro diatomic mamorekuru nonpolar, uye vasina covalent. Makemikari ehupfumi pamusoro halogens kuvabvumira kuti kuumba yeimwe neruzhinji zvinhu nyore, saka vari kumbobvira rinowanikwa vasina kusungwa muchimiro zvakasikwa. Fluoro - zvikuru rinoita halogen uye astatine - zvishoma.

All halogens boka Ndini ndinoumba munyu zvakafanana ehupfumi. In yeimwe izvi, halides varipo somunhu halide anion ane nokuchengeta -1 (semuenzaniso, Cl -, Br -). Kugumisa -id chinoratidza kuvapo halide anions; semuenzaniso Cl - inonzi "chloride".

Uyezve, makemikari ehupfumi ose halogens kuvabvumira kuita sezvo oxidizing yomuchipatara - oxidized simbi. Most nemakemikari chokuita halogens - redox mu aqueous mhinduro. Halogens vanoumba vasina ukama kabhoni kana senitrogen mu Organic yeimwe, apo ukuru oxidation (CO) akaenzana -1. Kana akazova munhu halogen atomu covalently akasungwa rehydrogen atomu pachinhu makemikari remubatanidzwa denderedzwa rechiedza chivakashure aitwe Kazhinji, kana prefixes fluoro-, chloro-, bromo-, iodo- - chaizvo halogens. Halogen zvinhu angava crisscross chisungo kuti aumbe diatomic mamorekuru pamwe polar zvisungo covalent kuroorwa.

Kuiisa chlorine (Cl 2) raiva rokutanga halogen yakavhurwa 1774, panguva iyoyo akazarura ayodhini (I 2), bromine (Br 2), fluorine (F 2) uye astatine (Panguva, vakawana rokupedzisira pana 1940 Yg). The zita "halogen" rinobva pashoko rechiGiriki mudzi hal- ( «munyu») uye -Gen ( «chimiro"). Pamwe chete, mashoko aya anoreva "munyu-dzichiumbwa", kusimbisa chokwadi chokuti halogen ikasakendenga pamwe simbi kuumbika munyu. Halite - zita padombo munyu, dzinongoitika chicherwa anoumbwa yavaibvisa chloride (NaCl). Pakupedzisira, halogen inoshandiswa pamba - rine fluoride mu mushonga wemazino, chloro disinfect kunwa mvura, ayodhini uye kunoita kukura thyroid mahormone.

zvine maatomu akafanana

Fluoro - chinhu pamwe mabhomba nhamba 9, runotaurwa naF The zvokuvamba fluorine yakatanga yakawanikwa 1886 d kubudikidza nevamwe kubva hydrofluoric acid.. In vakasununguka mamiriro riripo iri muchimiro fluoro diatomic mamorekuru (F 2) uye ndicho halogen, ari goko. Fluoro - zvikuru electronegative che periodic table. At kamuri tembiricha, munhu rakachenuruka yeyero gasi. Fluorine ane zviduku mabhomba nharaunda. CO Its - -1 kunze zvokuvamba diatomic mamiriro umo ayo oxidation wehurumende iri razero. Fluoro zvikuru mishonga kushingaira uye interacts zvakananga zvinhu zvose kunze nehelium (Iye), neon (Ne) uye argon (Ar). The H 2 O mhinduro, hydrofluoric asidhi (Zvakanaka hf) ndiye simba acid. Kunyange zvikuru electronegative fluoro, ayo electronegativity haana kuziva acidity; Zvakanaka hf chinhu simba asidhi nokuti chokuti fluoride Ion kunokosha (ph> 7). Uyezve, fluoro unobereka oxidants simba chaizvo. Somuenzaniso, fluorine unogona sei pamwe inert gasi xenon nokuumba yakasimba oxidant xenon difluoride (XeF 2). Mafomu akawanda fluoride.

Kuiisa chlorine - chinhu pamwe mabhomba nhamba 17 uye makemikari chiratidzo Cl. Yakawanikwa 1774 ne g. Kusiyanisa kubva hydrochloric acid. In yayo zvokuvamba hurumende anoumba munhu diatomic Morekuru Cl 2. Kuiisa chlorine ane wandei SB -1, 1, 3, 5 uye 7. Panguva nzvimbo tembiricha zviri chiedza girini gasi. Sezvo chisungo inopfurwa pakati mbiri kuiisa chlorine maatomu, simba, Cl 2 morekuru ane zvikuru kukwanisa kupinda papi. Kuiisa chlorine ikasakendenga pamwe simbi yokuumba munyu, makatumidzwa chlorides. Chloride ions ndivo kupfuura zhinji ions zviri yomugungwa. Kuiisa chlorine anewo isotopes maviri: 35 Cl uye 37 Cl. Yavaibvisa chloride ndicho kubatana vose chlorides.

Bromine - makemikari chinhu chine maatomu nhamba 35 uye chiratidzo Br. Wakatanga yakawanikwa 1826 muchimiro chepuraimari bromine riri diatomic Morekuru, Br 2. At nzvimbo tembiricha, chiri yakatsvukuruka mashava zvokunwa. CO Its - -1, + 1, 3, 4 uye 5. Bromo zvakawanda kushingaira kupfuura ayodhini, asi vari sekwaserera pane kuiisa chlorine. Uyezve, Bromo isotope ane mbiri 79 Br uye 81 Br. Bromine rikaitika muchimiro munyu bromide, zvazvichanyungudutswa yomugungwa. Mumakore achangopfuura, kugadzirwa bromide munyika kwakawedzera yekudyidzana nemhaka ichiwanikwa, uye upenyu hurefu. Kufanana nevamwe halogens bromine uye oxidant zviri muchetura kwazvo.

Ayodhini - makemikari chinhu pamwe mabhomba nhamba 53 uye chiratidzo I. The ayodhini oxidation ane: -1, +1, +5 uye +7. Pane ari muchimiro diatomic Morekuru, I 2. At kamuri tembiricha nefuma chikukutu ndechevakura pepuru. Ayodhini ane kugadzikana isotope - 127 I. First yakawanikwa 1811, achibatsirwa algae uye sulfuric acid. Pari, ayodhini ions zvinogona voga mugungwa mvura. Pasinei chokwadi kuti ayodhini haisi chaizvo soluble mumvura, ayo solubility anogona ngazviwedzerwe paaishandisa vakaparadzana iodides. Ayodhini inoita basa rinokosha mumuviri, vachiita kugadzirwa thyroid mahormone.

Astatine - a radioactive chinhu chine maatomu nhamba 85 uye chiratidzo At. zvinogoneka oxidation Its rinoti -1, 1, 3, 5 uye 7. chete halogen kuti haisi diatomic Morekuru. Under kwomuzvarirwo ezvinhu, imwe esimbi rakaoma zvinhu dema. Astatine haiwanzowaniki chaizvo Kufananidzira, saka zvishoma zvinozivikanwa nezvake. Uyezve, astatine ane pfupi chaizvo hafu-upenyu, asisiri pane maawa mashoma. Akagamuchira muna 1940 pamusana kwetunhu. Zvinofungidzirwa kuti astatine yakafanana ayodhini. Ichazivikanwa esimbi ehupfumi.

Tafura pazasi chinoratidza nemamiriro halogen maatomu, nemamiriro rokunze paiva maerekitironi.

halogen

The configuration of Erekitironi

fluorine

1s 2 2s 2 2p 5

kuiisa chlorine

2 3s 3p 5

bromine

3d 10 4S 2 4p 5

ayodhini

4D 2 10 5s 5p 5

astatine

4f 14 5d 10 6s 2 6p 5

mamiriro kwakadaro kunokonzera chokunze paiva maerekitironi kuti mumuviri uye zvemakemikari zvivako yakafanana halogens. Zvisinei, kana tichienzanisa zvinhu izvi uye misiyano vakachengeta.

Periodic ehupfumi halogen boka

ehupfumi zvokunyama nyore zvinhu zviri halogen zvakachinja kuwedzera ordinal nhamba maatomu akafanana. Nokuti Absorção de Água nani uye makuru zvakajeka, tinopa iwe munhu matafura shoma.

Utsotso uye Kubika pfungwa iri boka inowedzerawo pamwe kuwedzera kukura Morekuru (F

Table 1. The halogens. Physical zvivako: utsotso uye Kubika pfungwa

halogen

Utsotso T (C)

Kubika T (C)

fluorine

-220

-188

kuiisa chlorine

-101

-35

bromine

-7,2

58,8

ayodhini

114

184

astatine

302

337

  • The mabhomba nharaunda inowedzerawo.

tsanga saizi kunowedzera (F

Table 2: Halogen. Physical ehupfumi: mabhomba radii

halogen

The covalent nharaunda (pm)

Ion (X -) siyana (pm)

fluorine

71

133

kuiisa chlorine

99

181

bromine

114

196

ayodhini

133

220

astatine

150

  • ionization simba shoma.

Kana kwokunze Valence maerekitironi havasi raiva pedyo musimboti, rokubviswa hakurevi yakawanda simba pazviri. Saka, simba rinodiwa kuti ejection rokunze Erekitironi haisi yakakwirira panzvimbo dzapasi chikamu boka zvinhu, sezvo pane zvakawanda simba mumatunhu. Uyezve, mukuru simba ionization kunokonzera chinhu kuratidza non-esimbi unhu. esimbi ehupfumi nokuti ionization simba ipfupi (At

Table 3. halogens. Physical ehupfumi: ionisation simba

halogen

The ionization simba (KJ / mol)

fluorine

na1681

kuiisa chlorine

1251

bromine

1140

ayodhini

1008

astatine

890 ± 40

  • Electronegativity kunoderedza.

Kuwanda Valence maerekitironi iri atomu kunowedzera pamwe kuwedzera simba mumatunhu ari mberi ezasi nhanho. Maerekitironi vari mberi mberi kubva chinoumba; Saka, mwoyo uye maerekitironi vari kwete vakwezvane. The kuwedzera kuongorora imomo. Naizvozvo Electronegativity shoma kuwedzera nguva (At

Table 4. halogens. Physical ehupfumi: electronegativity

halogen

electronegativity

fluorine

4.0

kuiisa chlorine

3.0

bromine

2.8

ayodhini

2.5

astatine

2.2

  • Erekitironi sungano kunoderedza.

Sezvo kukura ane atomu inowedzera pamwe kwenguva Erekitironi sungano iri kazhinji wakaderedzwa (B

Table 5. sungano halogen Erekitironi

halogen

Erekitironi sungano (KJ / mol)

fluorine

-328,0

kuiisa chlorine

-349,0

bromine

-324,6

ayodhini

-295,2

astatine

-270,1

  • Reactivity zvinhu kunoderedza.

Reactivity kuti halogen shoma kuwedzera nguva (At

Inorganic kemesitiri. Rehydrogen + halogens

Halide akaumba kana halogen iri akaita nevamwe, zvishoma electronegative maatomu akafanana kuumba binary akakura. Rehydrogen ikasakendenga pamwe halogens yokuumba halides HX mhando:

  • rehydrogen fluoride Zvakanaka hf;
  • chloride HCl;
  • rehydrogen bromide HBr;
  • rehydrogen iodide HI.

rehydrogen halides zviri nyore zvazvichanyungudutswa mvura kuumba hydrohalic (hydrofluoric, hydrochloric, hydrobromic, hydroiodic acid). The ehupfumi pamusoro acids izvi vanopiwa pazasi.

The acids inoumbwa zvinotevera maitiro: HX (aq) + H 2 O (l) → X - (aq) + H 3 Haiwa + (aq).

All halide rehydrogen kuti aumbe simba acid, kunze Zvakanaka hf.

Acidity inowedzera hydrohalic acids: Zvakanaka hf

Hydrofluoric asidhi anogona etch girazi nedzimwe fluorides inorganic yakareba.

Zvingaita sokuti musoro kuti Zvakanaka hf ndiye dukusa hydrohalic acid, sezvo fluorine pacharwo kumusoro electronegativity. Asi H-F chisungo chakasimba chaizvo, zvichiguma simba chaizvo acid. Ukama hwakasimba chinorondedzerwa nenzira pfupi chisungo urefu uye hombe dissociation simba. Zvose hydrogen halides Zvakanaka hf ane pfupi kubatana kureba kupfuura chisungo dissociation simba.

halogen oxoacids

Halogen oxo acids muri acids pamwe rehydrogen maatomu, okisijeni uye halogen. acidity yavo inogona tsunga nokuongorora chivako. Halogen oxoacids dzinoturwa pazasi:

  • Hypochlorous acid, HOCl.
  • Chlorous asidhi HClO 2.
  • Chloric asidhi HClO 3.
  • Perchloric asidhi HClO 4.
  • Hypobromous acid, HOBr.
  • Bromic acid, HBrO 3.
  • Perbromic asidhi HBrO 4.
  • Hypoiodous asidhi Hội.
  • Iodic iine acid HIO 3.
  • Metayodnaya asidhi HIO4, H5IO6.

In nechimwe izvi hwepurotoni acids vakasungwa bhodhoro atomu, saka fananidzo chisungo tsanga protons hazvibatsiri. Chikuru basa iri kuridzwa pano electronegativity. Acidity kunowedzera nokuwanda okisijeni maatomu waakaita kuti nechepakati atomu.

Pakuonekwa uye ezvinhu nyaya

The inokosha ehupfumi zviri halogens chaiko kwenguva pfupi kunogona kutaurwa zvinotevera tafura.

Fuma ezvinhu (pa nzvimbo tembiricha)

halogen

chitarisiko

simba

ayodhini

pepuru

astatine

dema

mvura-mvura

bromine

russet

gaseous

fluorine

akacheneruka shora mashava

kuiisa chlorine

girini akacheneruka

tsananguro chitarisiko

Ruvara nemhaka halogens Absorção de Água chiedza kuonekwa mamorekuru zvichikonzera maerekitironi manyawi. Fluoro absorbs Violet chiedza, uye somugumisiro anotarisa tsvuku rakachenuruka. Ayodhini, kusiyana, absorbs chiedza yeyero uye anotarisa pepuru (yeyero nezvishava - nopindirana mavara). Halogen ruvara rinokwidibira pamwe kuwedzera nguva.

The rakanamwa midziyo mvura bromine uye rakasimba ayodhini zviri zvakanyatsoenzana pamwe pamwando wawo, izvo zvinogona kuonekwa sechinhu gasi wechitema.

Kunyange zvazvo ruvara astatine isingazivikanwi, zvinonzi aidavira kuti kuva zvasviba ayodhini (t. E. Black) maererano kuchengetwa muenzaniso.

Zvino, kana ukabvunzwa: "Tsanangura ehupfumi ose halogens mumuviri," iwe uchati.

The mwero oxidation ose halogens mu yeimwe

The mwero oxidation inowanzoshandiswa pachinzvimbo "Valence kuti halogens." Kazhinji, asi oxidation mamiriro akaenzana -1. Asi kana halogen unesungano mumwe okisijeni kana halogen, zvingatora mamwe inoti: okisijeni -2 SB ane pokutanga. Kana vaviri vakasiyana halogen maatomu waakaita pamwe kupfuura electronegative atomu chinokurira uye anotora CO -1.

Somuenzaniso, muna ayodhini chloride (ICl) ndiro CO chloro -1, +1 uye ayodhini. Kuiisa chlorine zvikuru electronegative pane ayodhini, naizvozvo CO akaenzana -1.

The bromic asidhi (HBrO 4) okisijeni ane CO -8 (-2 X 4 = -8 atomu). Rehydrogen rine zvachose oxidation nhamba +1. Uyezve izvi tsika mbiri anopa CO -7. Sezvo mukomboni chokupedzisira SB inofanira kuva zero, asi CO ndiyo nomwe bromine.

Chechitatu anosiiwa mutemo uyu mwero oxidation zviri halogen iri zvokuvamba chimiro (X 2), apo ayo CO vakaenzana razero.

halogen

Munguva yeimwe ari CO

fluorine

-1

kuiisa chlorine

-1, +1, +3, +5, +7

bromine

-1, +1, +3, +4, +5

ayodhini

-1, +1, +5, +7

astatine

-1, +1, +3, +5, +7

Sei pamwe fluorine anogara -1?

Electronegativity kunowedzera nguva. Saka, zviri fluorine ane chikuru electronegativity pamusoro zvinhu zvose, sezvinoratidzwa panzvimbo yacho periodic table. Its zvemagetsi configuration 1s 2 2s 2 2p 5. Kana fluoride anowana mumwe Erekitironi, akanyanyisa peji orbitals azara zvachose uye dzinoumba octet wakakwana. Nekuti fluorine ane refu electronegativity, inogona kusarudza nyore imwe Erekitironi kubva yakavakidzana maatomu. Fluoride muchiitiko ichi isoelectronic inert gasi (pamwe sere Valence maerekitironi) uye zvose zvayo kwokunze orbitals akazara. In mamiriro ichi, fluorine zvakawanda yakatsiga.

Kugadzirira uye kushandisa halogens

Zvakasikwa, ari halogens vari panguva anion, saka vakasununguka halogen iri zvinoberekwa oxidation nokuda electrolysis kana oxidants. Somuenzaniso, kuiisa chlorine iri kunotangira hydrolysis kuti yavaibvisa chloride mhinduro. Kushandiswa halogens uye dzavo dzakasiyana-siyana yeimwe.

  • Fluoride. Pasinei chokwadi kuti fluorine iri reactive chaizvo, rinoshandiswa mumaindasitiri zhinji. Somuenzaniso, iwo musimboti chezvinonhuwira polytetrafluoroethylene (PTFE) uye dzimwe fluoropolymers. Chlorofluorocarbons vari Organic makemikari kuti kare rakashandiswa serimwe refrigerants uye propellants mu aerosols. Chikumbiro yavo yamira nokuda kwavo zvichibvira kukanganisa zvakatipoteredza. Vakatsiviwa hydrochlorofluorocarbons. Fluorine inowedzerwa mushonga wemazino (SnF 2) uye mvura yokunwa (NaF) kudzivirira mazino. The halogen zvirimowo mu ivhu akashandiswa kubudisa mamwe Ceramics (LiF), rakashandiswa simba renyukireya (UF 6) kuwana fluoroquinolone mushonga, alumina (Na 3 Alf 6) kuti mudziye mukuru voltage michina (SF 6).
  • Kuiisa chlorine kuwana rinoshandiswa zvakasiyana siyana. Rinoshandiswa kuti disinfection nokunwa mvura uye kushambira madziva. Yavaibvisa hypochlorite (NaClO) Nde chezvinonhuwira bleaching nevamiririri. Hydrochloric asidhi zvinowanzodavirwa kushandiswa bhizimisi uye mumarabhoritari. Kuiisa chlorine aripo polyvinyl chloride (PVC) uye dzimwe Polymers inoshandiswa kuputira waya, sepombi uye Electronics. Uyezve, kuiisa chlorine yave anobatsira neindasitiri inogadzira mishonga. Medicaments ine kuiisa chlorine, anoshandiswa kurapa zvirwere, chisimbwa uye chirwere cheshuga. Kwazvakarerekera hydrochloride chimiro - chimwe chezvinonhuwira zvinodhaka zvakawanda. Kuiisa chlorine chinoshandiswawo chenesa kuchipatara zvokushandisa uye disinfection. Mune zvokurima, kuiisa chlorine ari chezvinonhuwira zhinji ezvokutengeserana kwemishonga yezvipembenene DDT (dihlorodifeniltrihloretan) raishandiswa sechinhu zvokurima zvipembenene, asi kushandiswa kwayo kwakaregwa.

  • Bromine, nokuda kwayo nonflammability, kushandiswa tunodzivisa combustion. Rinewo methyl bromide, mumwe tupukanana inoshandiswa kuchengetera zvirimwa uye kudzvinyirira mabhakitiriya. Zvisinei, kushandisa kunyanyisa pane methyl bromide rave vakarega nemhaka kukanganisa dzayo ozone rukoko. Bromine rinoshandiswa kugadzirwa peturu, Photographic firimu, moto, mishonga kuti kurapwa nemabayo uye cheAlzheimer.
  • Ayodhini inoita basa rinokosha zvakakodzera kushanda thyroid shwanu. Kana muviri asingadi kuwana ayodhini zvakakwana, iyo thyroid shwanu inowedzerwa. Nokuti kudzivirira goiter vanoshingaira halogen vakanyanyisa tafura munyu. Ayodhini rinoshandiswawo sechinhu akambozvishandisa kuuraya utachiona. Ayodhini ari huri zvinogadzirisa akashandiswa wokunatswa maronda akazarurwa uye uyewo disinfecting bhurandi. Uyezve, sirivha iodide kunokosha mumufananidzo.
  • Astatine - pasi radioactive uye isingawanzowanikwi halogen, saka zvimwe harishandiswi. Zvinofungidzirwa kuti maatomu akafanana izvi zvinogona kubatsira ayodhini ari mutemo thyroid mahormone.

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